Early solar system aqueous activity: K isotope evidence from Allende

The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K₂O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ⁴¹K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K₂O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ⁴¹K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K₂O content and K isotope compositions (0.02–0.05 wt%; δ⁴¹K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation.     

基于LocaSpaceViewer的地理信息技术应用教学设计与反思

本文基于笔者运用LocaSpaceViewer软件完成人教版地理必修3“地理信息技术在区域地理环境研究中的应用”的教学内容,总结反思教学过程中出现的问题,并提出改进的建议和措施。     

贵州夜郎湖表层水体地球化学昼夜变化及其影响因素

为探究岩溶水库水文地球化学行为过程,对贵州普定夜郎湖表层水体进行了为期3 d的高分辨率昼夜监测。结果表明：1）多变的天气和水文条件叠加导致水体离子指标昼夜变化不显著,规律性较差。而水温、DO、pH值、SpC、SIc、pCO₂等常规理化指标受水温变化和生物作用表现出明显的昼夜波动。2）利用亨利常数和主成分分析,得到温度变化、生物作用、人类活动、水库的蓄水与放水对夜郎湖水库水文地球化学特征变化的贡献率分别为21.66%、17.28%、14.08%和10.22%,说明作用于水库水文地球化学行为的因子具有多元性。3）δ ¹⁸O表现出与DO一致的波动趋势,即白天上升,晚上下降,反映在短时间尺度上,氢氧稳定同位素变化受控于生物过程（主要是呼吸作用过程）;而对比水库水体和大气降水的d-excess（d值）发现,水库水体的d值（8.21‰）显著偏低于当地大气降水的d值（9.64‰）,说明在长时间尺度上,主要受蒸发效应引起的不平衡分馏影响。     

无水硝酸镁制备过程中的水解特性

在槽式太阳能热发电领域,硝酸镁基熔盐逐渐引起关注。通过六水硝酸镁煅烧法制备无水硝酸镁,采用拉曼、DSC与XRD表征脱水产物,系统研究了环境压力、脱水温度与时间对六水硝酸镁脱水和水解的影响。结果表明,六水硝酸镁在煅烧过程中水解为碱式硝酸镁Mg_3(OH)_4(NO_3)_2,在水溶液中进一步分解为Mg(OH)_2。随着煅烧温度和时间的增加,脱水产物中的含水量逐渐减少,同时水解产物Mg_3(OH)_4(NO_3)_2含量逐渐增加。真空环境下煅烧,可显著降低硝酸镁的水解反应。六水硝酸镁在真空环境下230℃煅烧1.5 h,所制备的无水硝酸镁中水解产物含量为3.63%。制备的硝酸镁可进一步用于硝酸镁基熔盐的研究。     

甘肃陇中黄土高原农业灌溉耗水系数监测试验研究

选择甘肃省临洮县洮惠渠灌区为试验研究区,通过直接观读、自动监测等技术手段,获取试验灌区的引水量、退水量、土壤墒情、降水量及蒸发量等水文基础数据。以水文监测基础数据为依据,采用引排差法、水分平衡法等相结合的方法,开展了农业灌溉耗水系数试验研究。初步试验结果表明:试验灌区灌溉期平均耗水系数为0. 730,典型地块灌溉期平均耗水系数为0. 671,2016年试验灌区降水量较常年偏少13. 0%~26. 3%,总体上属轻度干旱年份。该研究成果可为甘肃陇中黄土高原区水资源管理提供技术支撑。     

大数据驱动下的数字古地理重建：现状与展望

古地理学是一门强数据依赖性学科,古地理重建作为古地理学的核心任务之一,着眼于研究地质历史时期地球表面的地理、生物、气候面貌及其演化规律。随着大数据时代的来临,海量古地理数据的不断积累和计算机技术的高速发展使得标准化、智能化的数字古地理重建成为可能。文章通过介绍国内外与古地理相关的代表数据库及团队,总结其优缺点,提出大数据驱动下的数字古地理重建核心思路:(1)建立标准化的古地理学知识体系;(2)建立开放互动、动态更新的古地理数据库,并利用机器阅读技术等拓展数据来源;(3)建立标准化的古地理学数据质量控制体系;(4)利用机器学习技术建立各类型古地理重建模型,深度挖掘数据;(5)以可实时更新的智能数字地图集或多维动画形式输出成果。     

桂林-阳朔地区DEM地形特征与岩性相关性分析及分类研究

地形地貌是岩性解译的重要信息,地形因子作为描述DEM数字曲面几何特征的定量指标参数,可用来定量化表达不同岩性所在地区地形地貌特征。本文以桂林-阳朔地区为研究区,研究地形因子数学、地质意义,建立岩性与地形因子组合间的定量关联,进而实现岩石类型划分。本文基于ASTERGDEM提取坡度、起伏度等12个地形因子,在分析各个地形因子地质意义基础上,通过聚类分析及方差分析的多元统计分析方法,研究各岩性地形因子特性及其关联性,建立研究区岩性之间的定量差异;此外,利用因子分析方法研究岩性分类过程中的主导因素,确定适宜岩性分类方法以实现定量化岩性分类。实验结果表明：不同岩性、不同地形地貌的地形因子（组合）之间具有显著差异,基于因子分析得到的宏观地形复杂度指数（MTI）以及微观曲率指数（MCI）对岩石类型的分类精度达77.36%。研究表明,地形复杂度等地形因子可用于岩性分类,采用因子分析方法可获取反映地形地貌宏观、微观特征的定量指标,且岩性分类效果良好。     

Hydrological management strategies for the control of algal blooms in regulated lowland rivers

Reservoirs of lowland floodplain rivers with eutrophic backgrounds cause variations in the hydrological and hydraulic conditions of estuaries and low-dam reservoir areas, which can promote planktonic algae to proliferate and algal bloom outbreaks. Understanding the ecological effects of variations in hydrological and hydraulic processes in lowland rivers is important for algal bloom control. In this study, the middle and lower reaches of the Han River, China, a typical regulated lowland river with a eutrophic background, are selected. Based on the effect of hydrological and hydraulic variability on algal blooms, a hydrological management strategy for river algal bloom control is proposed. The results showed that (a) differences in river morphology and background nutrient levels cause significant differences in the critical threshold flow velocities for algal bloom outbreaks between natural river and low-dam reservoir sections; there is no uniform threshold flow velocity for algal bloom control. (b) There are significant differences in the river hydrological/hydraulic conditions between years with and without algal blooms. The average river flow, water level and velocity in years with algal blooms are significantly lower than those in years without algal blooms. (c) For different river sections where algal blooms occur and to meet the threshold flow velocities, the joint operation of cascade reservoirs and diversion projects is an effective method to prevent and control algal blooms in regulated lowland rivers. This study is expected to deepen our understanding of the ecological significance of special hydrological processes and guide algal bloom management in regulated lowland rivers.     

基于Sentinel-2的潮间红树林提取方法

位于潮间带的红树林可能在高潮时被海水淹没的特点，使得传统的植被提取方法在红树林信息提取方面存在局限性。本文在对比分析了出露的红树林、高潮水位淹没的红树林、海水水体的光谱特征后，提出了一种利用归一化潮间红树林指数（NIMI）提取潮间带红树林的方法。该指数是由植被强吸收的红波段，强反射的两个红边波段和近红外波段组成的归一化表达式。利用该指数对福建省龙海九龙江口湿地的红树林进行了分类提取，提取结果与高分二号影像目视验证和现场调查结果进行了对照。结果显示，该方法提取红树林的用户精度达到93.98%，并显著优于利用归一化水体指数（NDWI）、归一化植被指数（NDVI）及随机森林的结果。